This paper will show the results of the first experiments to get nano-clay clay composite materials based on modified polystyrene resin by melt - mix method. The intercalated nanocomposite structures are characterized by X-ray diffraction (XRD) and scanning electron microscope (SEM) techniques. Polystyrene nano-composites with 2% nanoclay by weight exhibit an increases about 10% in impact resistance and they also lower the water absortion (nearly 60% compared with polystyrene resin) without any significant loss of tensile strength, flexural strength and flexural modulus.