Some compounds of -aminoketone type have been synthesized by reaction between substituted benzylideneanilines and acetophenone in the present of hydrochloric acid as catalyst in the ethanol medium. These azomethines have been synthesized from substituted benzaldehydes and aniline. The structures of obtained -aminoketones have been confirmed by using spectroscopic methods (IR- and mass spectra). Their metallic corrosion inhibition properties also have been estimated on aluminum and CT-3 steel using immersion method.