Based on density measurements, partial and excess molar volumes for binary mixtures of nitrobenzene and benzaldehyde with three isomers of xylene have been measured. The whole range of composition and temperatures from T = ( to ) K at ambient pressure MPa, has been considered. The excess molar volumes were negative and decreased by increasing temperature for all mixtures which are explained based on intermolecular interactions. Excess molar volumes for solutions including nitrobenzene were absolutely larger than benzaldehyde binary mixtures. The partial and excess molar volumes for each component have been appraised and reported. The excess molar volumes have been successfully fitted to Redlich–Kister equation. | The study of partial and excess molar volumes for binary mixtures of nitrobenzene and benzaldehyde with xylene isomers from T = ( to ) K and P = MPa
