Two newly synthesized Schiff bases DMCA and DMBA were used for selective detection of Cd2+ over a wide range of other metal ions in acetonitrile (ACN)/Tris-HCl buffer (10 mM, pH , v/v 2:1). The sensors can detect Cd2+ ions by colour changes from colourless to orange for DMBA and yellow to reddish for DMCA. Response of the probes towards metal ions was investigated by using UV-vis spectroscopy. The complex stoichiometry between the sensors, DMBA and DMCA, and Cd 2+ was found to be 2:1 and the binding constants were calculated to be ×10 12M−2 and ×10 12M−2 , respectively. The absorbance-based detection limits of DMBA and DMCA were calculated as µM and µM, respectively. The sensors were also successfully applied to real samples. |
