Chemical syntheses of biodegradable polymers phần 1

1. Giới thiệu 2. Phương pháp tiếp cận cộng hóa trị 2,1. Lốp Halogenation của CNT . Hydro 2,3. Cycloadditions 2,4. Triệt để bổ sung . Electrophilic bổ sung . Bổ sung các hợp chất vô cơ 2,7. Ozonolysis 2,8. Mechanochemical Functionalizations . Kích hoạt Plasma 2,10. Ái nhân bổ sung . Ghép của Polymers . | Chem. Rev. 2006 106 1105-1136 1105 Chemistry of Carbon Nanotubes Dimitrios Tasis 1 Nikos Tagmatarchis Alberto Bianco and Maurizio Prato Department of Materials Science University of Patras 26504 Rio Patras Greece Theoretical and Physical Chemistry Institute National Hellenic Research Foundation 48 Vass. Constantinou Avenue 116 35 Athens Greece Institut de Biologie Moléculaire etCellulaire UPR9021 CNRS Immunologie et Chimie Thereppettquué 66008Stresboore Frencc andDíppriímeétodíScíeézeFarmaacetícCh Universita di Trieite Piazzale Europp 1 f 41 2 Tnesse Itall Received July 12 2005 Contents 1. Introduction 1105 2. Covalent Approaches 1105 . Sidewall Halogenation of CNT 1105 . Hydrogenation 1107 . Cycloadditions 1107 . Radical Additions 1109 . Electrophilic Additions 1111 . Addition of Inorganic Compounds 1111 . Ozonolysis 1111 . Mechanochemical Functionalizations 1111 . Plasma Activation 1112 . Nucleophilic Additions 1112 . Grafting of Polymers 1112 . Grafting to Method 1112 . Grafting from Method 1112 3. Defect Site Chemistry 1113 . Amidation Esterification Reactions 1113 . Attachment of Biomolecules 1115 . Grafting of Polymers to Oxidized Nanotubes 1116 4. Noncovalent Interactions 1117 . Polymer Composites 1117 . Epoxy Composites 1117 . Acrylates 1118 . Hydrocarbon Polymers 1119 . Conjugated Polymers 1119 . Other Nanotube-Polymer Composites 1120 . Interactions with Biomolecules and Cells 1122 5. Endohedral Filling 1125 . Encapsulation of Fullerene Derivatives and 1125 Inorganic Species . Encapsulation of Biomolecules 1126 . Encapsulation of Liquids 1127 6. Concluding Remarks 1127 7. Acknowledgments 1127 8. References 1127 1. Introduction The unidirectional growth of materials to form nanowires or nanotubes has attracted enormous interest in recent years. t Department of Materials Science 26504 Rio Patras Greece. Telephone 30 2610 969929. Fax 30 2610 969368. E-mail .