Báo cáo hóa học: " Atomic Layer Deposition of ZnO on Multi-walled Carbon Nanotubes and Its Use for Synthesis of CNT–ZnO "

Tuyển tập báo cáo các nghiên cứu khoa học quốc tế ngành hóa học dành cho các bạn yêu hóa học tham khảo đề tài: Atomic Layer Deposition of ZnO on Multi-walled Carbon Nanotubes and Its Use for Synthesis of CNT–ZnO | Nanoscale Res Lett 2010 5 1836-1840 DOI s11671-010-9721-z NANO EXPRESS Atomic Layer Deposition of ZnO on Multi-walled Carbon Nanotubes and Its Use for Synthesis of CNT-ZnO Heterostructures X. L. Li C. Li Y. Zhang D. P. Chu W. I. Milne H. J. Fan Received 7 June 2010 Accepted 26 July 2010 Published online 7 August 2010 The Author s 2010. This article is published with open access at Abstract In this article direct coating of ZnO on PEC-VD-grown multi-walled carbon nanotubes MWCNTs is achieved using atomic layer deposition ALD . Transmission electron microscopy investigation shows that the deposited ZnO shell is continuous and uniform in contrast to the previously reported particle morphology. The ZnO layer has a good crystalline quality as indicated by Raman and photoluminescence PL measurements. We also show that such ZnO layer can be used as seed layer for subsequent hydrothermal growth of ZnO nanorods resulting in branched CNT-inorganic hybrid nanostructures. Potentially this method can also apply to the fabrication of ZnO-based hybrid nanostructures on other carbon nanomaterials. Keywords ZnO Atomic layer deposition Carbon nanotubes Hybrid nanomaterials Hydrothermal Solar cells Introduction Carbon nanotube CNT and inorganic composite materials have attracted much attention recently due to their potential application such as in photocatalyst gas sensors supercapacitors and field emission devices 1 . It has been reported X. L. Li H. J. Fan Division of Physics and Applied Physics School of Physical and Mathematical Sciences Nanyang Technological University 21 Nanyang Link Singapore 637371 Singapore e-mail fanhj@ C. Li Y. Zhang D. P. Chu W. I. Milne Electrical Engineering Division Engineering Department University of Cambridge 9 JJ Thomson Avenue CB3 0FA Cambridge Uk 0 Springer that the optical and electrical properties of CNT-inorganic composites can be enhanced compared to the individual constituents 2 . For example CNT films when

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