The Fe-MCM-22 zeolite was successfully synthesized with hexametylenimine template. Several physicochemical techniques (XRD, SEM, BET, AAS, IR and ESR) have been used to characterize this zeolite. Iron exists under three states: Isolated ions in tetrahedral lattice positions, in octahedral coordination as isolated ions at cationic positions and as aggregated oxide species or hydroxide phases.