Lead dioxide has been electrodeposited onto 304 stainless steel in three-solution with different compound and pH by ganvanostatic method. The X-Ray diffraction and scanning electron microscopy (SEM) techniques have been used to determine morphologic structure of lead dioxide. The obtained results have shown that lead dioxide has two forms crystal and, the faradic yield of electrodeposition process lead dioxide in the acid and alkali solution is more than in the neutral solution.