A new spectrophotometric method has been developed for determination of molybdenum using surfactantmediated liquid–liquid extraction. Molybdenum(V) obtained by ascorbic acid reduction in M H2 SO4 reacted spontaneously with thiocyanate and cetyl trimethyl ammonium bromide (CTAB), forming an intense orange yellow complex that was extracted quantitatively into 1,2-dichloroethane and absorbed at 460 nm. The absorbance of the extract was found to be stable for more than 24 h. |
