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Exploring inhibition of chemiluminescence mechanisms with fluorescence quenching studies and interaction energy calculations

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Carbamates weaken the luminol-H2O2 chemiluminescence (CL) catalyzed by sodium copper chlorophyll (SCC). The capacity to inhibit the CL of three carbamates is in the order of carbaryl (CBL) >carbofuran (CBF) >metolcarb (MTC). Mechanisms of carbamates inhibiting SCC-luminol-H2O2 CL are investigated using fluorescence quenching and quantum chemistry simulations for the first time in this work. Carbamate-SCC interactions studied using fluorescence spectroscopy show that with the increasing concentration of the SCC, the fluorescence of carbamate is quenched regularly, and the quenching mechanism is a static quenching process. |