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Colorimetric cadmium ion detection in aqueous solutions by newly synthesized Schiff bases

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Two newly synthesized Schiff bases DMCA and DMBA were used for selective detection of Cd2+ over a wide range of other metal ions in acetonitrile (ACN)/Tris-HCl buffer (10 mM, pH 7.32, v/v 2:1). The sensors can detect Cd2+ ions by colour changes from colourless to orange for DMBA and yellow to reddish for DMCA. Response of the probes towards metal ions was investigated by using UV-vis spectroscopy. The complex stoichiometry between the sensors, DMBA and DMCA, and Cd 2+ was found to be 2:1 and the binding constants were calculated to be 2.65×10 12M−2 and 4.95×10 12M−2 , respectively. The absorbance-based detection limits of DMBA and DMCA were calculated as 0.438 µM and 0.102 µM, respectively. The sensors were also successfully applied to real samples. |