Transparent heat mirror thin films have high transmittance in the visible range of wavelength and high reflectance in the infrared range of wavelength. TiO2/TiN/TiO2 films prepared via a reactive magnetron sputtering method on Corning glass and Alkali glass substrates, serve as transparent heat mirrors. The outer TiO2 layer has both the photo-catalytic and anti-reflective properties. The experiment data showed that the film thickness required for photocatalytic properties exceeds 350nm.